Short-circuit boundary conditions in ferroelectricPbTiO3thin films

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Short-circuit boundary conditions in ferroelectric PbTiO3 thin films

We examine the application of short-circuit electrical boundary conditions in density-functional theory calculations of ferroelectric thin films. Modeling PbTiO3 films with metallic electrodes, we demonstrate that under periodic boundary conditions of supercells, short-circuit conditions for the electrodes are equivalently satisfied in two repeated slab geometries: a PbTiO3/metal superlattice g...

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ژورنال

عنوان ژورنال: Physical Review B

سال: 2006

ISSN: 1098-0121,1550-235X

DOI: 10.1103/physrevb.74.054112